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Key Topics

How Materials Deform

Contrasting three fundamental behaviors:

  1. Elastic Solids - Store energy, recover shape
  2. Viscous Fluids - Dissipate energy, flow continuously
  3. Viscoelastic Materials - Combine both behaviors

1. Elastic (Hookean) Behavior

Defining Characteristics

Hooke’s Law:

Where:

  • σ = stress (force per unit area)
  • E = Young’s modulus (material stiffness)
  • ε = strain (fractional deformation)

Key Properties:

  • Stress proportional to strain (not rate)
  • Deform under load but store energy
  • Recover original shape when load removed
  • Energy stored elastically (like a spring)

Examples

  • Spring
  • Rubber band (small extension)
  • Steel beam (small deformations)
  • Hard plastic below glass transition temperature

Stress-Strain Curves

Linear Elastic Regime:

  • Straight line
  • Slope = Young’s modulus E
  • Higher E → more stress needed for same strain (stiffer)

Shear Modulus:

  • For shear deformations: τ = G·γ
  • G = shear modulus
  • Similar concept, different geometry

Typical Moduli Values

  • Steel: E ~ 200 GPa (very stiff)
  • Rubber: E ~ 1 MPa (soft)
  • Silicone gel: E ~ 50 kPa (very soft)
  • Brain tissue: E ~ 1 kPa (extremely soft)

2. Viscous (Newtonian) Behavior

Defining Characteristics

Newton’s Law of Viscosity:

Where:

  • τ = shear stress
  • η = viscosity (Pa·s)
  • = shear rate (strain rate)

Key Properties:

  • Stress proportional to strain rate (not strain itself)
  • Flows continuously under any applied stress
  • Dissipates energy as heat (irreversible)
  • No shape recovery when stress removed

Examples

  • Water (η ≈ 1 mPa·s)
  • Honey (η ≈ 10 Pa·s, ~10,000× water)
  • Glycerol (η ≈ 1 Pa·s)
  • Motor oil

Dimensional Analogy

PropertyElasticViscous
Relationσ = E·ετ = η·
UnitsPa = N/m²Pa·s
Response toStrainStrain rate
EnergyStoredDissipated

Behavior Under Load

  • If you stop applying stress to viscous fluid:
    • Deformation continues until stress is zero
    • No recovery
    • Fluid remains in deformed state

3. Viscoelastic Behavior

Combined Characteristics

Definition: Materials exhibiting both elastic and viscous behaviors

  • Deform like elastic solid on short timescales
  • Flow like viscous fluid over long times
  • Behavior depends on observation timescale

Common Viscoelastic Materials

  • Polymers (quintessential examples)
  • Biological tissues (cartilage, muscle, skin)
  • Gels
  • Silly putty (classic demo material)
  • Many food products (dough, cheese, etc.)

Spring-Dashpot Models

Maxwell Model

Configuration: Spring and dashpot in series

Represents: Fluid with memory

Behavior:

  • Can relax stress over time
  • If sudden strain applied and held:
    • Initially: High stress (spring compressed)
    • Over time: Stress gradually decays (dashpot flows)
    • Eventually: Stress → 0 (full relaxation)

Equation:

Relaxation Time:

Kelvin-Voigt Model

Configuration: Spring and dashpot in parallel

Represents: Solid that creeps under load

Behavior:

  • Under sudden load:
    • No instantaneous elastic jump (dashpot resists)
    • Gradual spring deformation (creep)
    • Approaches equilibrium asymptotically
  • When load removed:
    • Slow recovery back to original shape

Equation:

Retardation Time:

Stress Relaxation and Creep

Stress Relaxation

Experiment:

  1. Apply sudden fixed strain
  2. Hold constant
  3. Measure stress vs time

Results:

  • Elastic material: Constant stress (no decay)
  • Viscoelastic (Maxwell): Stress decays exponentially
  • Time constant = relaxation time

Creep

Experiment:

  1. Apply constant stress
  2. Measure strain vs time

Results:

  • Elastic: Immediate strain, then constant
  • Viscous: Strain increases linearly forever
  • Viscoelastic (Kelvin-Voigt):
    • Immediate dashpot resistance
    • Gradual approach to equilibrium

Relaxation Time Concept

Definition

Relaxation Time (τ): Characteristic time for material to transition from elastic to viscous response

Physical Meaning:

  • Maxwell time: τ = η/E
  • Time for stress to decay to 1/e of initial value
  • Separates elastic (short-term) and viscous (long-term) regimes

Time-Scale Dependence

Fast Observation (t << τ):

  • Material behaves elastic (solid-like)
  • Dashpot “frozen” (hasn’t had time to flow)
  • Spring dominates

Slow Observation (t >> τ):

  • Material behaves viscous (liquid-like)
  • Spring equilibrated
  • Dashpot flows freely

Application to Silly Putty:

  • τ ~ few seconds
  • Quick poke (t << τ): Bounces like ball (elastic)
  • Slow pull (t >> τ): Flows like liquid (viscous)

Examples and Case Studies

Silly Putty Demonstration

Classic Demo:

Fast Impact (High Strain Rate):

  1. Roll into ball
  2. Drop from height
  3. Bounces like elastic ball
  4. Behavior: Solid-like (t << τ)

Slow Deformation (Low Strain Rate):

  1. Take same putty
  2. Slowly pull apart
  3. Flows and strands out like liquid
  4. Can form thin filament that necks
  5. Behavior: Liquid-like (t >> τ)

Very Fast (Brittle Failure):

  • Quick yank → snaps (brittle behavior)
  • Elastic domination with insufficient time for viscous flow

Metal vs Polymer Comparison

Metal Spring:

  • Apply weight briefly
  • Springs back immediately
  • Pure elastic response
  • Negligible viscous component

Viscoelastic Polymer Strip:

  • Apply same weight
  • Might slowly rebound
  • Or not fully recover if short time
  • Clear viscoelastic behavior

Pitch Drop Experiment

Famous Long-Term Experiment:

Short Timescale (Impact):

  • Block of pitch (tar)
  • Hit with hammer → shatters
  • Feels solid, elastic

Long Timescale (Years):

  • Over ~10 years, drops form and fall out
  • Flows like extremely viscous liquid
  • Demonstrates extreme relaxation time (years!)

Lesson: Time scale of observation matters!

Quantitative Example

Dynamic Testing:

  • Water: Phase angle δ ≈ 90° (all viscous, no elastic storage)
  • Rubber: Phase angle δ ≈ 0° (all elastic storage)
  • Silly putty: Phase angle δ ≈ 45° at intermediate frequencies (half-half)

Units Reminder:

  • Elastic modulus: Pa
  • Viscosity: Pa·s
  • Example values:
    • Rubber E ~ 1 MPa
    • Honey η ~ 10 Pa·s
    • Silly putty τ ~ seconds

Learning Outcomes

Students will be able to:

  1. Differentiate elastic vs viscous response

    • State defining constitutive relations (Hooke’s law vs Newton’s viscosity law)
    • Qualitatively describe behavior under load
  2. Give examples of each type

    • Elastic: Steel, hard plastic below , rubber (small strains)
    • Viscous: Water, oil, glycerin
    • Viscoelastic: Silly putty, cartilage, polymer melt
    • Justify classifications
  3. Understand viscoelastic models

    • Maxwell model: Initial stress from spring, then decays as dashpot flows
    • Kelvin-Voigt: Sudden stress → dashpot resistance + gradual spring deformation
    • Conceptual understanding (no ODE solving required)
  4. Interpret storage vs loss qualitatively

    • Viscoelastic material has:
      • Storage modulus (elastic part, energy stored)
      • Loss modulus (viscous part, energy dissipated)
    • More elastic → bounces back (stores energy)
    • More viscous → damps motion (loses energy as heat)
  5. Apply time-scale reasoning

    • Predict material behavior based on deformation rate
    • Quick stretch → stiff (elastic)
    • Slow stretch → soft/flowy (viscous)
    • Articulate relaxation time concept

Discussion Questions

1. Identify Behaviors

Scenarios to classify:

  • Bowling ball impacts cement floor and rebounds

    • Mostly elastic (some energy lost)
  • Person slowly sinking into memory foam mattress

    • Viscoelastic (slow deformation over time)
  • Toothpaste extruded from tube

    • Mostly viscous flow (with yield stress)
  • Guitar string vibrating

    • Elastic

Task: Students debate and justify answers

2. Spring vs Dashpot Analogy

Questions:

  • If you stretch Maxwell material (spring+dashpot series) and hold, what happens to stress?

    • Initially: High stress from spring
    • Over time: Gradually decays (dashpot relieves it)
    • Stress relaxation
  • If suddenly released after long hold, will it return to original length?

    • No – dashpot has flowed (permanent deformation)
    • Only spring part returns
    • Some deformation remains
  • How does this differ from Kelvin-Voigt under sudden load?

3. Energy Storage vs Loss

Scenario: Two materials feel similarly stiff when tapped, but one gets warm when bent repeatedly, the other doesn’t.

Question: What does this indicate?

  • Warming material: Dissipating energy → higher loss modulus
  • Non-warming: Stores-returns energy → higher storage modulus

Examples:

  • Rubber bands heating up after stretching
  • Car tires heating up (viscoelastic damping)

4. Design Considerations

Shoe Sole for Runners:

  • More elastic or more viscous?
  • Discussion:
    • Elastic: Returns energy (spring in step)
    • Viscous: Absorbs energy (shock absorption)
    • Likely want mix (viscoelastic)
    • Different answers possible
    • Shows engineering balance

Seismic Dampers:

  • Should be highly viscous
  • Dissipate earthquake energy
  • Not elastic (would spring back and forth)
  • Connects material behavior to function

Key Concepts to Remember

Elastic Behavior

  • Relation: σ = E·ε
  • Energy: Stored (recoverable)
  • Response: Immediate
  • Examples: Springs, metals, rubber (small strain)

Viscous Behavior

  • Relation: τ = η·
  • Energy: Dissipated as heat
  • Response: Continuous flow
  • Examples: Water, honey, oils

Viscoelastic Behavior

  • Models: Maxwell (fluid-like) vs Kelvin-Voigt (solid-like)
  • Key parameter: Relaxation time τ = η/E
  • Time dependence: Solid when fast, liquid when slow
  • Examples: Polymers, silly putty, tissues

Storage vs Loss

  • Storage modulus (G’): Elastic energy stored
  • Loss modulus (G”): Viscous energy dissipated
  • Phase angle (δ): tan δ = G”/G’
  • Sets up next lecture on rheology!

Preparation for Next Lecture

Next lecture: Rheology – Measuring “Softness”

Consider:

  • How do we experimentally measure these properties?
  • What is a rheometer?
  • How do G’ and G” relate to oscillatory tests?
  • What does “soft” really mean quantitatively?

References

  1. “What is a Viscoelastic material?” - Biolin Scientific
  2. Ferry, J.D. “Viscoelastic Properties of Polymers” (1980)
  3. Lakes, R.S. “Viscoelastic Materials” (2009)
  4. Newtonian fluid - Wikipedia

Previous Lecture: Lecture 4: Finite-Time Singularities
Next Lecture: Lecture 6: Sheets, Bubbles and Drops
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