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Key Topics
How Materials Deform
Contrasting three fundamental behaviors:
- Elastic Solids - Store energy, recover shape
- Viscous Fluids - Dissipate energy, flow continuously
- Viscoelastic Materials - Combine both behaviors
1. Elastic (Hookean) Behavior
Defining Characteristics
Hooke’s Law:
Where:
- σ = stress (force per unit area)
- E = Young’s modulus (material stiffness)
- ε = strain (fractional deformation)
Key Properties:
- Stress proportional to strain (not rate)
- Deform under load but store energy
- Recover original shape when load removed
- Energy stored elastically (like a spring)
Examples
- Spring
- Rubber band (small extension)
- Steel beam (small deformations)
- Hard plastic below glass transition temperature
Stress-Strain Curves
Linear Elastic Regime:
- Straight line
- Slope = Young’s modulus E
- Higher E → more stress needed for same strain (stiffer)
Shear Modulus:
- For shear deformations: τ = G·γ
- G = shear modulus
- Similar concept, different geometry
Typical Moduli Values
- Steel: E ~ 200 GPa (very stiff)
- Rubber: E ~ 1 MPa (soft)
- Silicone gel: E ~ 50 kPa (very soft)
- Brain tissue: E ~ 1 kPa (extremely soft)
2. Viscous (Newtonian) Behavior
Defining Characteristics
Newton’s Law of Viscosity:
Where:
- τ = shear stress
- η = viscosity (Pa·s)
= shear rate (strain rate)
Key Properties:
- Stress proportional to strain rate (not strain itself)
- Flows continuously under any applied stress
- Dissipates energy as heat (irreversible)
- No shape recovery when stress removed
Examples
- Water (η ≈ 1 mPa·s)
- Honey (η ≈ 10 Pa·s, ~10,000× water)
- Glycerol (η ≈ 1 Pa·s)
- Motor oil
Dimensional Analogy
| Property | Elastic | Viscous |
|---|---|---|
| Relation | σ = E·ε | τ = η· |
| Units | Pa = N/m² | Pa·s |
| Response to | Strain | Strain rate |
| Energy | Stored | Dissipated |
Behavior Under Load
- If you stop applying stress to viscous fluid:
- Deformation continues until stress is zero
- No recovery
- Fluid remains in deformed state
3. Viscoelastic Behavior
Combined Characteristics
Definition: Materials exhibiting both elastic and viscous behaviors
- Deform like elastic solid on short timescales
- Flow like viscous fluid over long times
- Behavior depends on observation timescale
Common Viscoelastic Materials
- Polymers (quintessential examples)
- Biological tissues (cartilage, muscle, skin)
- Gels
- Silly putty (classic demo material)
- Many food products (dough, cheese, etc.)
Spring-Dashpot Models
Maxwell Model
Configuration: Spring and dashpot in series
Represents: Fluid with memory
Behavior:
- Can relax stress over time
- If sudden strain applied and held:
- Initially: High stress (spring compressed)
- Over time: Stress gradually decays (dashpot flows)
- Eventually: Stress → 0 (full relaxation)
Equation:
Relaxation Time:
Kelvin-Voigt Model
Configuration: Spring and dashpot in parallel
Represents: Solid that creeps under load
Behavior:
- Under sudden load:
- No instantaneous elastic jump (dashpot resists)
- Gradual spring deformation (creep)
- Approaches equilibrium asymptotically
- When load removed:
- Slow recovery back to original shape
Equation:
Retardation Time:
Stress Relaxation and Creep
Stress Relaxation
Experiment:
- Apply sudden fixed strain
- Hold constant
- Measure stress vs time
Results:
- Elastic material: Constant stress (no decay)
- Viscoelastic (Maxwell): Stress decays exponentially
- Time constant
= relaxation time
Creep
Experiment:
- Apply constant stress
- Measure strain vs time
Results:
- Elastic: Immediate strain, then constant
- Viscous: Strain increases linearly forever
- Viscoelastic (Kelvin-Voigt):
- Immediate dashpot resistance
- Gradual approach to equilibrium
-
Relaxation Time Concept
Definition
Relaxation Time (τ): Characteristic time for material to transition from elastic to viscous response
Physical Meaning:
- Maxwell time: τ = η/E
- Time for stress to decay to 1/e of initial value
- Separates elastic (short-term) and viscous (long-term) regimes
Time-Scale Dependence
Fast Observation (t << τ):
- Material behaves elastic (solid-like)
- Dashpot “frozen” (hasn’t had time to flow)
- Spring dominates
Slow Observation (t >> τ):
- Material behaves viscous (liquid-like)
- Spring equilibrated
- Dashpot flows freely
Application to Silly Putty:
- τ ~ few seconds
- Quick poke (t << τ): Bounces like ball (elastic)
- Slow pull (t >> τ): Flows like liquid (viscous)
Examples and Case Studies
Silly Putty Demonstration
Classic Demo:
Fast Impact (High Strain Rate):
- Roll into ball
- Drop from height
- Bounces like elastic ball
- Behavior: Solid-like (t << τ)
Slow Deformation (Low Strain Rate):
- Take same putty
- Slowly pull apart
- Flows and strands out like liquid
- Can form thin filament that necks
- Behavior: Liquid-like (t >> τ)
Very Fast (Brittle Failure):
- Quick yank → snaps (brittle behavior)
- Elastic domination with insufficient time for viscous flow
Metal vs Polymer Comparison
Metal Spring:
- Apply weight briefly
- Springs back immediately
- Pure elastic response
- Negligible viscous component
Viscoelastic Polymer Strip:
- Apply same weight
- Might slowly rebound
- Or not fully recover if short time
- Clear viscoelastic behavior
Pitch Drop Experiment
Famous Long-Term Experiment:
Short Timescale (Impact):
- Block of pitch (tar)
- Hit with hammer → shatters
- Feels solid, elastic
Long Timescale (Years):
- Over ~10 years, drops form and fall out
- Flows like extremely viscous liquid
- Demonstrates extreme relaxation time (years!)
Lesson: Time scale of observation matters!
Quantitative Example
Dynamic Testing:
- Water: Phase angle δ ≈ 90° (all viscous, no elastic storage)
- Rubber: Phase angle δ ≈ 0° (all elastic storage)
- Silly putty: Phase angle δ ≈ 45° at intermediate frequencies (half-half)
Units Reminder:
- Elastic modulus: Pa
- Viscosity: Pa·s
- Example values:
- Rubber E ~ 1 MPa
- Honey η ~ 10 Pa·s
- Silly putty τ ~ seconds
Learning Outcomes
Students will be able to:
-
Differentiate elastic vs viscous response
- State defining constitutive relations (Hooke’s law vs Newton’s viscosity law)
- Qualitatively describe behavior under load
-
Give examples of each type
- Elastic: Steel, hard plastic below
, rubber (small strains) - Viscous: Water, oil, glycerin
- Viscoelastic: Silly putty, cartilage, polymer melt
- Justify classifications
- Elastic: Steel, hard plastic below
-
Understand viscoelastic models
- Maxwell model: Initial stress from spring, then decays as dashpot flows
- Kelvin-Voigt: Sudden stress → dashpot resistance + gradual spring deformation
- Conceptual understanding (no ODE solving required)
-
Interpret storage vs loss qualitatively
- Viscoelastic material has:
- Storage modulus (elastic part, energy stored)
- Loss modulus (viscous part, energy dissipated)
- More elastic → bounces back (stores energy)
- More viscous → damps motion (loses energy as heat)
- Viscoelastic material has:
-
Apply time-scale reasoning
- Predict material behavior based on deformation rate
- Quick stretch → stiff (elastic)
- Slow stretch → soft/flowy (viscous)
- Articulate relaxation time concept
Discussion Questions
1. Identify Behaviors
Scenarios to classify:
-
Bowling ball impacts cement floor and rebounds
- Mostly elastic (some energy lost)
-
Person slowly sinking into memory foam mattress
- Viscoelastic (slow deformation over time)
-
Toothpaste extruded from tube
- Mostly viscous flow (with yield stress)
-
Guitar string vibrating
- Elastic
Task: Students debate and justify answers
2. Spring vs Dashpot Analogy
Questions:
-
If you stretch Maxwell material (spring+dashpot series) and hold, what happens to stress?
- Initially: High stress from spring
- Over time: Gradually decays (dashpot relieves it)
- Stress relaxation
-
If suddenly released after long hold, will it return to original length?
- No – dashpot has flowed (permanent deformation)
- Only spring part returns
- Some deformation remains
-
How does this differ from Kelvin-Voigt under sudden load?
3. Energy Storage vs Loss
Scenario: Two materials feel similarly stiff when tapped, but one gets warm when bent repeatedly, the other doesn’t.
Question: What does this indicate?
- Warming material: Dissipating energy → higher loss modulus
- Non-warming: Stores-returns energy → higher storage modulus
Examples:
- Rubber bands heating up after stretching
- Car tires heating up (viscoelastic damping)
4. Design Considerations
Shoe Sole for Runners:
- More elastic or more viscous?
- Discussion:
- Elastic: Returns energy (spring in step)
- Viscous: Absorbs energy (shock absorption)
- Likely want mix (viscoelastic)
- Different answers possible
- Shows engineering balance
Seismic Dampers:
- Should be highly viscous
- Dissipate earthquake energy
- Not elastic (would spring back and forth)
- Connects material behavior to function
Key Concepts to Remember
Elastic Behavior
- Relation: σ = E·ε
- Energy: Stored (recoverable)
- Response: Immediate
- Examples: Springs, metals, rubber (small strain)
Viscous Behavior
- Relation: τ = η·
- Energy: Dissipated as heat
- Response: Continuous flow
- Examples: Water, honey, oils
Viscoelastic Behavior
- Models: Maxwell (fluid-like) vs Kelvin-Voigt (solid-like)
- Key parameter: Relaxation time τ = η/E
- Time dependence: Solid when fast, liquid when slow
- Examples: Polymers, silly putty, tissues
Storage vs Loss
- Storage modulus (G’): Elastic energy stored
- Loss modulus (G”): Viscous energy dissipated
- Phase angle (δ): tan δ = G”/G’
- Sets up next lecture on rheology!
Preparation for Next Lecture
Next lecture: Rheology – Measuring “Softness”
Consider:
- How do we experimentally measure these properties?
- What is a rheometer?
- How do G’ and G” relate to oscillatory tests?
- What does “soft” really mean quantitatively?
References
- “What is a Viscoelastic material?” - Biolin Scientific
- Ferry, J.D. “Viscoelastic Properties of Polymers” (1980)
- Lakes, R.S. “Viscoelastic Materials” (2009)
- Newtonian fluid - Wikipedia
Previous Lecture: Lecture 4: Finite-Time Singularities
Next Lecture: Lecture 6: Sheets, Bubbles and Drops
Course Home: Course Overview
Metadata
Author:: Vatsal Sanjay
Date published:: Jul 19, 2026
Date modified:: Jul 19, 2026
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