Here, we only consider the continuum picture.
See 2.5-Conservation-Laws for first principle derivations
Key Topics
Bridging Microscopic to Continuum Description
Introduction to Coarse-Graining:
- How we average over many atoms/molecules to treat a material as continuous fields
- Density, velocity, etc. on scales large compared to molecular size
- Motivation for continuum view in soft matter
- Example: A polymer solution or foam modeled as a continuous medium despite discrete entities
Fundamental Conservation Laws
Derived via coarse-graining:
- Conservation of Mass (continuity equation)
- Conservation of Momentum (Newton’s second law in continuum form → Euler or Navier-Stokes equations)
- Conservation of Energy (first law of thermodynamics in continuum form)
Physical Meaning of Conservation Laws
Integral Form:
- What goes in minus what goes out = accumulation
Differential Form:
- Local divergence form
- Changes at a point due to flows or sources at that point
The Continuum Hypothesis
Assumptions:
- Material properties vary smoothly
- Can be defined at a “point” much larger than molecular scale
- Point must be small compared to system size
- Scales much larger than the mean free path of the molecules
.
Field Variables
Result of coarse-graining:
- Velocity field:
- Pressure:
- Density:
- etc.
Learning Outcomes
-
State the three main conservation laws
- Mass, momentum, energy in words
- Recognize their mathematical forms
-
Derive a basic continuity equation
- Starting from a small fixed volume
- Show that mass change = (mass in) – (mass out)
- Translate to:
-
Identify terms in momentum equation
- Understand:
- In words: mass×acceleration = forces from stress gradient + external forces
- Grasp where inertia, pressure, and viscosity enter
- Understand:
-
Connect to physical reasoning
- Apply conservation laws to simple scenarios
- Example: Squeezing toothpaste tube (mass conservation + incompressibility)
- Example: Fluid speeding up in narrow pipe (continuity with constant flow rate)
- Articulate local vs global conservation (nothing “teleports”)
Conservation Law Details
1. Conservation of Mass
Physical Statement: Mass cannot be created or destroyed (for systems without nuclear reactions or relativistic effects).
Integral Form:
Differential Form (Continuity Equation):
For incompressible fluids (constant density):
2. Conservation of Momentum
Physical Statement: Newton’s second law applied to a fluid element: Rate of change of momentum equals sum of forces.
Differential Form:
Where:
= material derivative (following fluid parcel) = stress tensor = external body forces (e.g., gravity)
For Newtonian fluids (Navier-Stokes):
3. Conservation of Energy
Physical Statement: First law of thermodynamics: Change in energy equals heat added plus work done.
Differential Form:
Where:
= specific internal energy = heat flux = viscous dissipation term
Examples and Case Studies
Mass Conservation Example
Pipe Flow:
- Water flowing through a pipe that splits into two branches
- If 2 L/min enters, sum out of branches must be 2 L/min (steady state, incompressible)
- Illustrates:
Variable Cross-Section:
- If one branch is partially closed, water velocity increases there
- Smaller area → higher speed to satisfy continuity
- Analogous to blood flow speeding up in a narrowed artery
Momentum Conservation Example
Soft Gel in Slingshot:
- When stretched and released, momentum is transferred to the gel
- Causes it to fly
- Continuum terms: Internal elastic forces (stress) accelerated the gel’s mass
Stone in Pond:
- Dropping a stone in a pond
- Momentum from gravity and impact is redistributed via:
- Pressure waves (sound)
- Fluid motion
- Violating momentum conservation locally leads to observable flows
Energy Conservation Example
Silly Putty Ball:
- Dropped from height, deforms and warms slightly on impact
- Potential energy → deformation work + heat
- Illustrates energy bookkeeping
Mixing Fluids:
- Slow mixing of glycerol and water
- Mechanical work (stirring) dissipated as heat via viscous stress
- Internal energy increase consistent with energy conservation
Key Equations Summary
| Conservation Law | Differential Form | Key Insight |
|---|---|---|
| Mass | Local density change = net flux | |
| Momentum | Acceleration from stress + body forces | |
| Energy | Energy change = heat flux + work |
Key Concepts to Remember
- Coarse-graining: Averaging microscopic behavior to obtain continuum fields
- Field variables: Density, velocity, pressure as functions of position and time
- Local conservation: Changes at a point due to local fluxes/sources only
- Continuum hypothesis: Valid when system >> molecular scale
- Incompressibility: Common assumption for liquids (
)
References
- Continuity equation - Wikipedia: https://en.wikipedia.org/wiki/Continuity_equation
- Batchelor, G.K. “An Introduction to Fluid Dynamics” (1967)
- Landau & Lifshitz “Fluid Mechanics” (1987)
