CoMPhy Lab blogs

Here, we only consider the continuum picture.
See 2.5-Conservation-Laws for first principle derivations

Key Topics

Bridging Microscopic to Continuum Description

Introduction to Coarse-Graining:

  • How we average over many atoms/molecules to treat a material as continuous fields
  • Density, velocity, etc. on scales large compared to molecular size
  • Motivation for continuum view in soft matter
  • Example: A polymer solution or foam modeled as a continuous medium despite discrete entities

Fundamental Conservation Laws

Derived via coarse-graining:

  1. Conservation of Mass (continuity equation)
  2. Conservation of Momentum (Newton’s second law in continuum form → Euler or Navier-Stokes equations)
  3. Conservation of Energy (first law of thermodynamics in continuum form)

Physical Meaning of Conservation Laws

Integral Form:

  • What goes in minus what goes out = accumulation

Differential Form:

  • Local divergence form
  • Changes at a point due to flows or sources at that point

The Continuum Hypothesis

Assumptions:

  • Material properties vary smoothly
  • Can be defined at a “point” much larger than molecular scale
  • Point must be small compared to system size
  • Scales much larger than the mean free path of the molecules .

Field Variables

Result of coarse-graining:

  • Velocity field:
  • Pressure:
  • Density:
  • etc.

Learning Outcomes

  1. State the three main conservation laws

    • Mass, momentum, energy in words
    • Recognize their mathematical forms
  2. Derive a basic continuity equation

    • Starting from a small fixed volume
    • Show that mass change = (mass in) – (mass out)
    • Translate to:
  3. Identify terms in momentum equation

    • Understand:
    • In words: mass×acceleration = forces from stress gradient + external forces
    • Grasp where inertia, pressure, and viscosity enter
  4. Connect to physical reasoning

    • Apply conservation laws to simple scenarios
    • Example: Squeezing toothpaste tube (mass conservation + incompressibility)
    • Example: Fluid speeding up in narrow pipe (continuity with constant flow rate)
    • Articulate local vs global conservation (nothing “teleports”)

Conservation Law Details

1. Conservation of Mass

Physical Statement: Mass cannot be created or destroyed (for systems without nuclear reactions or relativistic effects).

Integral Form:

Differential Form (Continuity Equation):

For incompressible fluids (constant density):

2. Conservation of Momentum

Physical Statement: Newton’s second law applied to a fluid element: Rate of change of momentum equals sum of forces.

Differential Form:

Where:

  • = material derivative (following fluid parcel)
  • = stress tensor
  • = external body forces (e.g., gravity)

For Newtonian fluids (Navier-Stokes):

3. Conservation of Energy

Physical Statement: First law of thermodynamics: Change in energy equals heat added plus work done.

Differential Form:

Where:

  • = specific internal energy
  • = heat flux
  • = viscous dissipation term

Examples and Case Studies

Mass Conservation Example

Pipe Flow:

  • Water flowing through a pipe that splits into two branches
  • If 2 L/min enters, sum out of branches must be 2 L/min (steady state, incompressible)
  • Illustrates:

Variable Cross-Section:

  • If one branch is partially closed, water velocity increases there
  • Smaller area → higher speed to satisfy continuity
  • Analogous to blood flow speeding up in a narrowed artery

Momentum Conservation Example

Soft Gel in Slingshot:

  • When stretched and released, momentum is transferred to the gel
  • Causes it to fly
  • Continuum terms: Internal elastic forces (stress) accelerated the gel’s mass

Stone in Pond:

  • Dropping a stone in a pond
  • Momentum from gravity and impact is redistributed via:
    • Pressure waves (sound)
    • Fluid motion
  • Violating momentum conservation locally leads to observable flows

Energy Conservation Example

Silly Putty Ball:

  • Dropped from height, deforms and warms slightly on impact
  • Potential energy → deformation work + heat
  • Illustrates energy bookkeeping

Mixing Fluids:

  • Slow mixing of glycerol and water
  • Mechanical work (stirring) dissipated as heat via viscous stress
  • Internal energy increase consistent with energy conservation

Key Equations Summary

Conservation LawDifferential FormKey Insight
MassLocal density change = net flux
MomentumAcceleration from stress + body forces
EnergyEnergy change = heat flux + work

Key Concepts to Remember

  • Coarse-graining: Averaging microscopic behavior to obtain continuum fields
  • Field variables: Density, velocity, pressure as functions of position and time
  • Local conservation: Changes at a point due to local fluxes/sources only
  • Continuum hypothesis: Valid when system >> molecular scale
  • Incompressibility: Common assumption for liquids ()

References

  1. Continuity equation - Wikipedia: https://en.wikipedia.org/wiki/Continuity_equation
  2. Batchelor, G.K. “An Introduction to Fluid Dynamics” (1967)
  3. Landau & Lifshitz “Fluid Mechanics” (1987)